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perylenetetracarboxylic dianhydride : ウィキペディア英語版 | perylenetetracarboxylic dianhydride
Perylenetetracarboxylic dianhydride (PTCDA) is an organic compound used commercially as a precursor to pigments and dyes. It is generated by oxidative fusion of naphthalene dicarboxylic anhydride via naphthalimide. PTCDA reacts with amines to give a range of useful colorants.〔Hunger, K. and Herbst, W. (2012) "Pigments, Organic" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, Weinheim. 〕〔Greene, M. (2009) "Perylene Pigments", pp. 261–274 in High Performance Pigments, Wiley-VCH, Weinheim.〕 ==Structure==
PTCDA occurs in two crystalline forms, α and β. Both have the P21/c monoclinic symmetry and a relatively high for organic compounds density of ca. 1.7 g/cm3. Their lattice parameters are: ''a'' = 0.374 nm, ''b'' = 1.196 nm, ''c'' = 1.734 nm, ''γ'' = 98.8° for α and ''a'' = 0.378 nm, ''b'' = 1.930 nm, ''c'' = 1.077 nm, ''γ'' = 83.6° for β phase.
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